Suh, Sung-Eun published the artcileSite-Selective Copper-Catalyzed Azidation of Benzylic C-H Bonds, Product Details of C13H10F2, the publication is Journal of the American Chemical Society (2020), 142(26), 11388-11393, database is CAplus and MEDLINE.
Site selectivity represents a key challenge for non-directed C-H functionalization, even when the C-H bond is intrinsically reactive. Here, we report a copper-catalyzed method for benzylic C-H azidation of diverse mols. Exptl. and d. functional theory studies suggest the benzyl radical reacts with a CuII-azide species via a radical-polar crossover pathway. Comparison of this method with other C-H azidation methods highlights its unique site selectivity, and conversions of the benzyl azide products into amine, triazole, tetrazole, and pyrrole functional groups highlight the broad utility of this method for target mol. synthesis and medicinal chem.
Journal of the American Chemical Society published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C18H34N4O5S, Product Details of C13H10F2.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia