Page, Claire G. published the artcileQuaternary Charge-Transfer Complex Enables Photoenzymatic Intermolecular Hydroalkylation of Olefins, Recommanded Product: 3-Benzoylpropionicacid, the publication is Journal of the American Chemical Society (2021), 143(1), 97-102, database is CAplus and MEDLINE.
Intermol. C-C bond-forming reactions are underdeveloped transformations in the field of biocatalysis. Here we report a photoenzymic intermol. hydroalkylation of olefins catalyzed by flavin-dependent ‘ene’-reductases. Radical initiation occurs via photoexcitation of a rare high-order enzyme-templated charge-transfer complex that forms between an alkene, ¦Á-chloroamide, and flavin hydroquinone. This unique mechanism ensures that radical formation only occurs when both substrates are present within the protein active site. This active site can control the radical terminating hydrogen atom transfer, enabling the synthesis of enantioenriched ¦Ã-stereogenic amides. This work highlights the potential for photoenzymic catalysis to enable new biocatalytic transformations via previously unknown electron transfer mechanisms.
Journal of the American Chemical Society published new progress about 2051-95-8. 2051-95-8 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ketone, name is 3-Benzoylpropionicacid, and the molecular formula is C10H10O3, Recommanded Product: 3-Benzoylpropionicacid.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia