Bishop, Peter T.’s team published research in Dalton Transactions in | CAS: 22693-41-0

Dalton Transactions published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, SDS of cas: 22693-41-0.

Bishop, Peter T. published the artcileSubstituent dependence of the reactions of [RuCl2(PPh3)3] with bulky aromatic thiols, SDS of cas: 22693-41-0, the publication is Dalton Transactions (2006), 1267-1270, database is CAplus and MEDLINE.

2,4,6-Trialkylbenzenethiols (alkyl = Me (tmt), Et (tet), Pri (tipt)) react with [RuCl2(PPh3)3] to give Ru products with the alkyl substituents forming M-C ¦Ò bonds, carbene, carbene with a S ¦Á-heteroatom, agostic H interaction or a simple tetrahedral Ru(II) species, depending on the substituent. Thus, the preparation and crystal structure of [Ru(SC6H2Me2CH2)(tmt)2(PPh3)] (1), [Ru(SC6H2Me2CH)(tmt)(PPh3)2] (2), [Ru(SC6H2Me2CSC6H2Me3)(tmt)(PPh3)2] (3), [Ru(tet)3(PPh3)] (4) and [Ru(tipt)2(PPh3)2] (5) are reported.

Dalton Transactions published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, SDS of cas: 22693-41-0.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia