Beswick, Michael A. published the artcileMetal selection of ligand functionality in [(mes)2PO2Li¡¤2thf]2 and [{(Me3Si)2N}Cd{(mes)2P-O}2Li¡¤2thf] (mes = C6H2Me3-2,4,6), Recommanded Product: Dimesitylphosphine oxide, the publication is Chemical Communications (Cambridge) (1997), 583-584, database is CAplus.
The reaction of LiBu with [(mes)2P(H):O] affords the diorganophosphinate complex [(mes)2PO2Li¡¤2THF] (1) and [(mes)2PLi], however, addition of [Cd{N(SiMe3)2}2] to the mixture gives the diorganophosphinite complex [{(Me3Si)2N}Cd{(mes)2P-O}2Li¡¤2THF] (2). The formation of these complexes illustrates that the ligand functionality of 1 can be controlled by the character of the coordinated metal ion. 1 And 2 were characterized by x-ray crystallog. (1: triclinic, space group P1?, R1 = 0.045; 2: monoclinic, space group C2/c, R1 = 0.064).
Chemical Communications (Cambridge) published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C18H23OP, Recommanded Product: Dimesitylphosphine oxide.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia