Sasso, Barbara published the artcileSynthesis of ¦Ø-End Group Functionalized Poly(methyl methacrylate)s via RAFT Polymerization, Product Details of C10H6F17N, the publication is Macromolecules (Washington, DC, United States) (2010), 43(18), 7453-7464, database is CAplus.
“Living” poly(Me methacrylate) (PMMA), prepared by the RAFT technique, reacted with maleic anhydride to give succinic anhydride-terminated PMMA (SA-PMMA) in very high yield. The ¦Ø-terminal anhydride residues react in high yields with primary alcs., primary amines and aromatic amines. As examples, SA-PMMA reacted with 1H,1H,2H,2H-perfluorodecylamine to give a polymer containing 5.78% of fluorine; with Disperse Orange 3 to give a dye-labeled PMMA; with 9-hydroxymethylanthracene to give a fluorescently labeled PMMA; with norephedrine to give a polymer with a biol. active end group; and with 4,4′-diaminophenymethane to give amine-ended PMMA. The latter reacted smoothly with fluorescein isocyanate to give a fluorescently labeled PMMA. In these examples the fraction of polymer chains functionalized were in the range 75-95%. Allowing for the fact the starting PMMAs were up to 96% “living”, these loadings correspond to functionalization yields, for the anhydride addition plus the reaction with the nucleophiles, of 81-99%.
Macromolecules (Washington, DC, United States) published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Product Details of C10H6F17N.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia