Zhang, Yaxing published the artcileManganese(
Mn-Catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles was disclosed, which enabled the synthesis of a broad range of secondary amides I [R = Ph, 4-H3CC6H4, 3-MeoC6H4, etc.; R1 = Me, i-Pr, t-Bu, etc.; R2 = Me, Ph, 4-ClC6H4, etc.] in moderate to excellent yields under mild conditions. The interaction between Mn(III) and DDQ facilitates the oxidation and makes it highly efficient and selective.
Organic & Biomolecular Chemistry published new progress about 457-68-1. 457-68-1 belongs to catalysis-chemistry, auxiliary class Fluoride,Benzene, name is Bis(4-fluorophenyl)methane, and the molecular formula is C6H13NO2, Application In Synthesis of 457-68-1.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia